High-temperature microwave effects in liquid media

Authors

  • Alexander Voloshko SSI ”Institute for Single Crystals” of National Academy of Sciences of Ukraine, Lenin Ave., 60, Kharkiv 61001, Ukraine
  • Natalia Pinchukova SSI ”Institute for Single Crystals” of National Academy of Sciences of Ukraine, Lenin Ave., 60, Kharkiv 61001, Ukraine
  • Oleg Shishkin SSI ”Institute for Single Crystals” of National Academy of Sciences of Ukraine, Lenin Ave., 60, Kharkiv 61001, Ukraine V.N. Karazin Kharkiv National University, Svobody sq., 4, Kharkiv 61022, Ukraine
  • Valentin Chebanov SSI ”Institute for Single Crystals” of National Academy of Sciences of Ukraine, Lenin Ave., 60, Kharkiv 61001, Ukraine V.N. Karazin Kharkiv National University, Svobody sq., 4, Kharkiv 61022, Ukraine

DOI:

https://doi.org/10.17721/fujcV3I1P73-81

Keywords:

microwave irradiation, heating mode, non-linear interactions, high-boiling liquid, viscosity

Abstract

The heating behavior of high-boiling liquids under microwave (MW) irradiation was investigated. Linear and non-linear heating modes depending on the applied MW power level were observed. The non-linear interactions emerging at “high” power levels are ascribed to electromagnetic oscillations excitations resulting in non-linear heating speed growth and considerable decrease in energy input. The relationship between non-linearity degree and liquids’ viscosity was established. The observed effects have been shown to apply not only to mere heating, but also to high-temperature chemical reactions. Future perspectives and practical applications of the work are also discussed.

References

Kappe C, Stadler A. Microwaves in Organic and Medicinal Chemistry. Methods and Principles in Medicinal Chemistry 2005 https://doi.org/10.1002/3527606556

de la Hoz A, Díaz-Ortiz A, Moreno A. Microwaves in organic synthesis. Thermal and non-thermal microwave effects. Chem. Soc. Rev. 2005;34(2):164-178. https://doi.org/10.1039/b411438h

Loupy A, Microwaves in Organic Synthesis, 2nd ed., Wiley - VCH: Weinheim 2006. https://doi.org/10.1002/9783527619559.fmatter

Herrero M, Kremsner J, Kappe C. Nonthermal Microwave Effects Revisited: On the Importance of Internal Temperature Monitoring and Agitation in Microwave Chemistry. The Journal of Organic Chemistry 2008;73(1):36-47. https://doi.org/10.1021/jo7022697

Robinson J, Kingman S, Irvine D, Licence P, Smith A, Dimitrakis G, Obermayer D, Kappe C. Understanding microwave heating effects in single mode type cavities—theory and experiment. Phys. Chem. Chem. Phys. 2010;12(18):4750. https://doi.org/10.1039/b922797k

Antonio C, Deam R. Can “microwave effects” be explained by enhanced diffusion?. Phys. Chem. Chem. Phys. 2007;9(23):2976-2982. https://doi.org/10.1039/b617358f

Dudley G, Stiegman A, Rosana M. Correspondence on Microwave Effects in Organic Synthesis. Angewandte Chemie International Edition 2013;52(31):7918-7923. https://doi.org/10.1002/anie.201301539

Kappe C. Reply to the Correspondence on Microwave Effects in Organic Synthesis. Angewandte Chemie International Edition 2013;52(31):7924-7928. https://doi.org/10.1002/anie.201304368

Landau LD, Lifshitz YM, Electrodynamics of continua (Theoretical Physics, Vol. VIII), 4th ed., Physmatlit Moscow, 2003.

Pinchukova N, Chebanov V, Gorobets N, Gudzenko L, Ostras K, Shishkin O, Hulshof L, Voloshko A. Beneficial energy-efficiencies in the microwave-assisted vacuum preparation of polyphosphoric acid. Chemical Engineering and Processing: Process Intensification 2011;50(11-12):1193-1197. https://doi.org/10.1016/j.cep.2011.08.009

Okress E. INTRODUCTION. Microwave Power Engineering 1968:378. https://doi.org/10.1016/b978-1-4831-9679-4.50043-4

Rukhadze A, Silin V. Kinetic theory of drift-dissipative instabilities of a plasma. Usp. Fiz. Nauk 1968;96(9):87-126. https://doi.org/10.3367/ufnr.0096.196809e.0087

Voitsenya VS, Voloshko AYu, Solodovchenko SI, Shtan' AF. Effect of ion viscosity on shear stabilization of drift dissipative instability. JETP Letters 1997;26:220.

Downloads

Published

2015-03-10

Issue

Vol. 3 No. 1 (2015)

Section

Articles

License

Copyright (c) 2015 French-Ukrainian Journal of Chemistry

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The French‑Ukrainian Journal of Chemistry holds copyright and publishes all articles under a Creative Commons Attribution 4.0 International licence (CC BY 4.0).
This license permits unrestricted use, sharing, adaptation, distribution, and reproduction in any medium or format, provided that the original author(s) and source are credited, a link to the license is included, and any changes made are indicated.
Authors grant the French‑Ukrainian Journal of Chemistry the exclusive right of first publication and may enter into separate, non‑exclusive distribution agreements for the published version (e.g., institutional repository, book chapter). Authors are also encouraged to post pre‑prints and post‑prints online to increase visibility and citation.